These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: A simple fluorophore-imine ensemble for colorimetric and fluorescent detection of CN- and HS- in aqueous solution.
    Author: Lakshmi PR, Kumar PS, Elango KP.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2020 Mar 15; 229():117974. PubMed ID: 31927478.
    Abstract:
    Colorimetric and fluorescent detection of cyanide and hydrogen sulfide ions has been effected using a simple organic probe in H2O:DMSO (20:80, v/v) medium. The probe exhibits a colour change from pale-yellow to red upon addition of these analytes under normal light and fluorescent change from green to red under UV lamp. Other competitive ions show no observable colour or fluorescence change. The binding constants of cyanide and hydrogen sulfide ions with the probe determined using fluorescence titration data are found to be 2.1 × 104 and 1.6 × 104 M-1, respectively. The probe fluorimetrically detects the analytes in a wide pH range (4-10). 1H and 13C NMR studies suggest that the probe senses cyanide ion through deprotonation and nucleophilic addition mechanism and hydrogen sulfide ion via deprotonation mechanism. Detection limits of cyanide and hydrogen sulfide are determined to be 0.15 and 1 μM, respectively. The practical utility of the probe has been demonstrated by same dual mode detection of cyanide in food materials like bitter almond, cassava flour and sprouting potato.
    [Abstract] [Full Text] [Related] [New Search]