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  • Title: Development of Perylene-Based Non-Fullerene Acceptors through Bay-Functionalization Strategy.
    Author: Fujimoto K, Takahashi M, Izawa S, Hiramoto M.
    Journal: Materials (Basel); 2020 May 06; 13(9):. PubMed ID: 32384804.
    Abstract:
    Perylene has had a tremendous impact in the history of material research for the molecular semiconductors. Among numerous derivatives of this polyaromatic hydrocarbon, perylene diimide (PDI) represents a promising class of organic materials envisioned as non-fullerene acceptors (NFAs) for the practical organic photovoltaic (OPV) applications due to their enhanced photo- and thermal stability and remarkably high electron affinity, some of which realize band-like transport properties. The present review guides some of the representative achievements in the development of rationally designed PDI systems, highlighting synthetic methodologies based on bay-functionalization strategies for creating well-designed molecular nanostructures and structure-performance relationship of perylene-based small molecular acceptors (SMAs) for the photovoltaic outcomes.
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