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  • Title: Universal size ratios of Gaussian polymers with complex architecture: radius of gyration vs hydrodynamic radius.
    Author: Haydukivska K, Blavatska V, Paturej J.
    Journal: Sci Rep; 2020 Aug 24; 10(1):14127. PubMed ID: 32839515.
    Abstract:
    We study the impact of arm architecture of polymers with a single branch point on their structure in solvents. Many physical properties of polymer liquids strongly dependent on the size and shape measures of individual macromolecules, which in turn are determined by their topology. Here, we use combination of analytical theory, based on path integration method, and molecular dynamics simulations to study structural properties of complex Gaussian polymers containing [Formula: see text] linear branches and [Formula: see text] closed loops grafted to the central core. We determine size measures such as the gyration radius [Formula: see text] and the hydrodynamic radii [Formula: see text], and obtain the estimates for the size ratio [Formula: see text] with its dependence on the functionality [Formula: see text] of grafted polymers. In particular, we obtain the quantitative estimate of the degree of compactification of these polymers with increasing number of closed loops [Formula: see text] as compared to linear or star-shape molecules of the same total molecular weight. Numerical simulations corroborate theoretical prediction that [Formula: see text] decreases towards unity with increasing f. These findings provide qualitative description of polymers with complex architecture in [Formula: see text] solvents.
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