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  • Title: Interfacial Strain Release from the WS2 /CsPbBr3 van der Waals Heterostructure for 1.7 V Voltage All-Inorganic Perovskite Solar Cells.
    Author: Zhou Q, Duan J, Yang X, Duan Y, Tang Q.
    Journal: Angew Chem Int Ed Engl; 2020 Dec 01; 59(49):21997-22001. PubMed ID: 32856367.
    Abstract:
    Perovskite lattice distortion induced by residual tensile strain from the thermal expansion mismatch between the electron-transporting layer (ETL) and perovskite film causes a sluggish charge extraction and transfer dynamics in all-inorganic CsPbBr3 perovskite solar cells (PSCs) because of their higher crystallization temperatures and thermal expansion coefficients. Herein, the interfacial strain is released by fabricating a WS2 /CsPbBr3 van der Waals heterostructure owing to their matched crystal lattice structure and the atomically smooth dangling bond-free surface to act as a lubricant between ETL and CsPbBr3 perovskite. Arising from the strain-released interface and condensed perovskite lattice, the best device achieves an efficiency of 10.65 % with an ultrahigh open-circuit voltage of 1.70 V and significantly improved stability under persistent light irradiation and humidity (80 %) attack over 120 days.
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