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  • Title: A twofold interpenetrating two-dimensional zinc(II) coordination polymer: synthesis, crystal structure and physical properties.
    Author: Chen NN, Zhang C, Tao JQ.
    Journal: Acta Crystallogr C Struct Chem; 2020 Sep 01; 76(Pt 9):850-855. PubMed ID: 32887854.
    Abstract:
    A novel twofold interpenetrating two-dimensional (2D) ZnII coordination framework, poly[[(μ-1,3-bis(2-methyl-1H-imidazol-1-yl)benzene-κ2N3:N3)(μ-naphthalene-2,6-dicarboxylato-κ2O2:O6)zinc(II)] dimethylformamide monosolvate], {[Zn(C12H6O4)(C14H14N4)]·C3H7NO}n or {[Zn(1,3-BMIB)(NDC)]·DMF}n (I), where H2NDC is naphthalene-2,6-dicarboxylic acid, 1,3-BMIB is 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene and DMF is dimethylformamide, was prepared and characterized through IR spectroscopy, elemental analysis, thermal analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that (I) exhibits an unusual twofold interpenetrating 2D network. In addition, it displays strong fluorescence emissions and a high photocatalytic activity for the degradation of Rhodamine B (RhB) under UV-light irradiation.
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