These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Synthesis of poly(2-hydroxypropyl methacrylate) latex particles via aqueous dispersion polymerization.
    Author: Ali AMI, Pareek P, Sewell L, Schmid A, Fujii S, Armes SP, Shirley IM.
    Journal: Soft Matter; 2007 Jul 17; 3(8):1003-1013. PubMed ID: 32900050.
    Abstract:
    Poly(2-hydroxypropyl methacrylate) latexes were prepared by aqueous dispersion polymerization at 60 °C using poly(-vinylpyrrolidone) [PNVP] as a steric stabilizer. The mean latex diameter can be controlled over a wide range by varying the synthesis parameters (initiator type, stabilizer concentration, addition of co-surfactant or comonomer), and narrow size distributions were observed in most cases. These sterically-stabilized latex particles were characterized by electron microscopy, dynamic light scattering, Malvern Mastersizer and FT-IR spectroscopy. The presence of the PNVP stabilizer at the surface of the latex particles was confirmed by X-ray photoelectron spectroscopy and the stabilizer content was assessed by H NMR spectroscopy and nitrogen microanalyses. Colloidally stable surfactant-stabilized poly(2-hydroxypropyl methacrylate) latexes could also be prepared in the absence of any PNVP stabilizer. Since 2-hydroxypropyl methacrylate contains a small amount of dimethacrylate impurity, these latexes are actually lightly cross-linked; their degree of swelling in DO, d-methanol and d-pyridine was investigated using dynamic light scattering and H NMR spectroscopy. Finally, three ionic water-soluble comonomers were successfully copolymerized with 2-hydroxypropyl methacrylate under aqueous dispersion conditions, as judged by aqueous electrophoresis studies.
    [Abstract] [Full Text] [Related] [New Search]