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  • Title: Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel.
    Author: Huang X, Teng S, Chi YR, Xu W, Pu M, Wu YD, Zhou JS.
    Journal: Angew Chem Int Ed Engl; 2021 Feb 08; 60(6):2828-2832. PubMed ID: 33140526.
    Abstract:
    Nickel-catalyzed intermolecular Heck reaction of cycloalkenes proceeds well with aryl triflates, mesylates and tosylates in excellent enantiomeric ratios. The asymmetric reductive Heck reaction also works with a 2-cyclopentenone ketal, which is equivalent to conjugate arylation of the enone itself.
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