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Title: Highly Compressible, Thermally Conductive, yet Electrically Insulating Fluorinated Graphene Aerogel. Author: Zhang C, Huang R, Wang P, Wang Y, Zhou Z, Zhang H, Wu Z, Li L. Journal: ACS Appl Mater Interfaces; 2020 Dec 30; 12(52):58170-58178. PubMed ID: 33337132. Abstract: Carbon-based aerogels have drawn substantial attention for a wide scope of applications. However, the high intrinsic electrical conductivity limits their potential thermal management application in electronic packaging materials. Herein, a highly compressible, thermally conductive, yet electrically insulating fluorinated graphene aerogel (FGA) is developed through a hydrofluoric acid-assisted hydrothermal process. The macroscopic-assembled FGA constituting of tailored interconnected graphene networks with tunable fluorine coverage shows excellent elasticity and fatigue resistance for compression, despite a low density of 10.6 mg cm-3. Moreover, the aerogel is proved to be highly insulating, with the observed lowest electrical conductivity reaching 4 × 10-7 S cm-1. Meanwhile, the aerogel exhibits prominent heat dissipation performance in a typical cooling procedure, which can be used to fabricate thermoconductive polymer composites for electronic packaging.[Abstract] [Full Text] [Related] [New Search]