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  • Title: Preparation of a GO/MIL-101(Fe) Composite for the Removal of Methyl Orange from Aqueous Solution.
    Author: Liu Z, He W, Zhang Q, Shapour H, Bakhtari MF.
    Journal: ACS Omega; 2021 Feb 23; 6(7):4597-4608. PubMed ID: 33644567.
    Abstract:
    The composite material graphene oxide (GO)/MIL-101(Fe) was prepared by a simple one-pot reaction method. MIL-101(Fe) grown on the surface of a GO layer was confirmed by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). The adsorption performance and the mechanism of MIL-101(Fe) and GO/MIL-101(Fe) for methyl orange (MO) were studied. The results have shown that the adsorption capacity of GO/MIL-101(Fe) for MO was significantly better than that of MIL-101(Fe), and its capacity was the highest when 10% GO was added. The Langmuir specific surface areas of MIL-101(Fe) and GO/MIL-101(Fe) were 1003.47 and 888.289 m2·g-1, respectively. The maximum adsorption capacities of MO on MIL-101 (Fe) and 10% GO/MIL-101 (Fe) were 117.74 and 186.20 mg·g-1, respectively. The adsorption isotherms were described by the Langmuir model, and the adsorption kinetic data suggested the pseudo-second order to be the best fit model. GO/MIL-101(Fe) can be reused at least three times.
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