These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Enhanced activity of vanadia supported on microporous titania for the selective catalytic reduction of NO with NH3: Effect of promoters.
    Author: Jeon SW, Song I, Lee H, Kim DH.
    Journal: Chemosphere; 2021 Jul; 275():130105. PubMed ID: 33676281.
    Abstract:
    Vanadium oxide-based catalysts are considered a promising catalyst for selective catalytic reduction (SCR) of NO with NH3, which is an effective NOx removal technology. As environmental issues have garnered more attention, however, improvements to vanadium-based SCR catalysts are strongly required. In a previous study, we found that vanadium oxide on microporous titania as a support (V/MPTiO2) has certain advantages, such as improved thermal stability and more suppressed N2O formation, over the use of conventional nanoparticle titania (DT-51) as a support. In this study, widely used promoters, such as W, Sb, and Mo, were added to V/MPTiO2 to investigate whether they have promoting effects on V/MPTiO2 as well. Among these promoters added catalysts, the W and Mo were found to have significant promoting effects on the enhancement of deNOx activities at low temperatures, while the addition of Sb to V/MPTiO2 tended to have a negative effect on the SCR activity. Based on the characterizations, including laser Raman, H2-temperature programmed reduction (H2-TPR), and in situ diffuse reflectance infrared Fourier transform (in situ DRIFT) analysis, we found that the addition of W and Mo increased the degree of polymerization in V/MPTiO2, which generated more reactive vanadia species. Hence, such changes, resulting from the addition of W and Mo promoters to V/MPTiO2, yielded enhanced catalytic activity at low temperatures.
    [Abstract] [Full Text] [Related] [New Search]