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  • Title: Visible-Light-Driven, Palladium-Catalyzed Heck Reaction of Internal Vinyl Bromides with Styrenes.
    Author: Li Y, Liu H, Huang Z, He Y, Xu BH, Wang H, Yu Z.
    Journal: J Org Chem; 2021 Jun 18; 86(12):8402-8413. PubMed ID: 34043916.
    Abstract:
    Functionalized 1,3-dienes were efficiently accessed from visible-light-driven, palladium-catalyzed Heck reaction of S,S-functionalized internal vinyl bromides with styrenes under mild conditions. This Heck reaction showcased tolerance of a wide array of functional groups, afforded the target products in moderate to excellent yields through a radical reaction pathway. The resultant diene products could be further transformed to highly functionalized trisubstituted furan derivatives.
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