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  • Title: Photoinduced Palladium-Catalyzed Intermolecular Radical Cascade Cyclization of N-Arylacrylamides with Unactivated Alkyl Bromides.
    Author: Du J, Wang X, Wang H, Wei J, Huang X, Song J, Zhang J.
    Journal: Org Lett; 2021 Aug 06; 23(15):5631-5635. PubMed ID: 34236201.
    Abstract:
    A mild visible-light-induced Pd-catalyzed intermolecular radical cascade reaction of N-arylacrylamides with unactivated alkyl bromides is disclosed. Photoexcited Pd complexes transfer a single electron in this protocol, and hybrid alkyl Pd-radical species are involved as the key reaction intermediates. Sophisticated bioactive oxindole derivatives bearing various substituents and substitution patterns can be efficiently afforded through this approach.
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