These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Preparation of 2D Graphene/MXene nanocomposite for the electrochemical determination of hazardous bisphenol A in plastic products.
    Author: Rajendran J, Kannan TS, Dhanasekaran LS, Murugan P, Atchudan R, ALOthman ZA, Ouladsmane M, Sundramoorthy AK.
    Journal: Chemosphere; 2022 Jan; 287(Pt 2):132106. PubMed ID: 34507149.
    Abstract:
    Bisphenol A (BPA) is one of the major contaminants with significant health hazards, which could also affect the endocrine system or induce cancer. It is essential to develop a highly sensitive and selective BPA sensor for environmental and food safety. Herein, 2D hybrid graphene/Ti3C2Tx nanocomposite (Gr/MXene) was prepared via a top-down method and then used to fabricate an electrochemical BPA sensor. The X-ray diffraction spectrometer (XRD) and Raman spectroscopy analysis were carried out to verify the successful formation of Gr sheets with MXene. The high resolution scanning electron microscopy (HR-SEM) was revealed the formation of MXene, and Gr/MXene nanocomposite. Furthermore, the 2D hybrid Gr/MXene nanocomposite modified glassy carbon electrode (GCE) was prepared for BPA oxidation in 100 mM phosphate buffer solution (PBS). Under the optimized condition, the Gr/MXene/GCE was displayed a linear range of detection from 10 to 180 nM and 1 to 10 μM BPA with the detection limits of 4.08 nM and 0.35 μM by amperometry and differential pulse voltammetry (DPV), respectively. Moreover, the proposed Gr/MXene modified electrode exhibited excellent stability, selectivity, repeatability and reproducibility towards the BPA detection. As a proof of concept, Gr/MXene modified sensor was effectively used to detect BPA in modern plastic products with the recovery ranging from 99.2 to 104.5%.
    [Abstract] [Full Text] [Related] [New Search]