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  • Title: Facile fabrication of metal-organic framework derived Fe/Fe3O4/FeN/N-doped carbon composites coated with PPy for superior microwave absorption.
    Author: Ma M, Bi Y, Jiao Z, Yue J, Liao Z, Wang Y, Ma Y, Huang W.
    Journal: J Colloid Interface Sci; 2022 Feb 15; 608(Pt 1):525-535. PubMed ID: 34626994.
    Abstract:
    At present, the magnetic metal/carbon composites have been widely explored for microwave absorption (MA), which effectively integrate the characteristics of magnetic and dielectric materials. As a typical material, metal-organic framework (MOF) shows tremendous potential as a precursor or template. However, its development is limited by the inferior impedance matching. Herein, a novel rod-like Fe/Fe3O4/FeN/N-doped carbon (FON/NC) composite was synthesized via dual-ligand strategy and following calcination. The outer polypyrrole (PPy) shell, obtained by a facile polymerization method, effectively optimized the impedance matching and observably enhanced the MA capacity. Both the multi-component loss mechanism and unique porous core-shell structures of MOF-derived composites were beneficial for microwave attenuation. The effects of filler loadings (20 wt%, 25 wt%, 30 wt% and 35 wt%) on electromagnetic (EM) properties of FON/NC@PPy composites were discussed. Remarkably, as-obtained composites exhibited a minimum reflection loss (RL) value of -60.08 dB at the layer thickness of merely 1.44 mm and the widest effective absorption bandwidth (EAB, RL ≤ -10 dB) of 5.06 GHz at 1.64 mm with 30 wt% filler loading. This work provides a great reference for designing MOF-derived absorbers with high MA performance.
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