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  • Title: Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal-Organic Framework Heterostructures.
    Author: Gu Z, Zhang W, Pan T, Shen Y, Qin P, Zhang P, Li X, Liu L, Li L, Fu Y, Zhang W, Huo F.
    Journal: Research (Wash D C); 2021; 2021():9854946. PubMed ID: 34877539.
    Abstract:
    Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core-shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites.
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