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Title: Zwitterionic hydrogel modified reduced graphene oxide/ZnO nanocomposite blended membrane with high antifouling and antibiofouling performances. Author: Zhang W, Huang H, Bernstein R. Journal: J Colloid Interface Sci; 2022 May; 613():426-434. PubMed ID: 35042040. Abstract: Membrane fouling and biofouling are major challenges in the application of membrane technology for wastewater treatment. The synthesis of antifouling and antibiofouling dual functionality membranes is a promising approach to tackling these problems. In this work, we fabricated a high-efficiency dual functionality polyethersulfone (PES) ultrafiltration membrane by blending an antibacterial reduced graphene oxide-ZnO nanocomposite into a PES matrix (rGO/ZnO-PES) followed by surface grafting of a low-fouling polyampholyte hydrogel (rGO/ZnO-z-PES). The antibacterial activity of the blended membrane was optimized by changing the nanocomposite fraction in the PES dope solution. Surface characterizations (SEM-EDS, XPS, ATR-FTIR, contact angle, and Zeta potential) confirmed the successful grafting of the zwitterionic hydrogel on the rGO/ZnO-PES membrane surface. Contact killing assays revealed that the polyampholyte hydrogel grafting did not affect the high antibacterial activity of the rGO/ZnO-PES membrane. Dynamic filtration experiments demonstrated the very high antifouling and antibiofouling of the rGO/ZnO-z-PES membrane, and significantly higher than those of the rGO/ZnO-PES and pristine PES membranes. The measured concentration of zinc ions in the permeate was low. Overall, our results demonstrate that the rGO/ZnO-z-PES membrane has excellent antifouling and antibiofouling performance and is stable and safe, and therefore very promising for wastewater treatment.[Abstract] [Full Text] [Related] [New Search]