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  • Title: Development of Methods to the Synthesis of β-Boryl Acyls, Imines and Nitriles.
    Author: Das KK, Mahato S, Hazra S, Panda S.
    Journal: Chem Rec; 2022 Apr; 22(4):e202100290. PubMed ID: 35088513.
    Abstract:
    Organoboron compounds are highly important and versatile synthetic intermediates for the preparation of a wide range of organic molecules. Organoboron compounds have drawn significant attention among organic chemists due to their Lewis acidic property, non-toxicity, and commercial availability. Over the last several decades, there has been a substantial development of new organoboron compounds, useful in organic synthesis. Among all other organoboron compounds, β-boryl carbonyl compounds are the important ones. The β-boryl compounds have appeared as promising intermediates for various synthetic transformations. The 1,4-conjugate addition of diboron reagents to carbon-carbon double bond in the presence of different transition-metal catalysts has been extensively reported by various research groups across the globe. This mini-review outlines the numerous racemic as well as asymmetric β-borylation methods developed to date.
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