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  • Title: Polyacrylonitrile-Reinforced Composite Gel Polymer Electrolytes for Stable Potassium Metal Anodes.
    Author: Zhang Y, Bahi A, Ko F, Liu J.
    Journal: Small; 2022 Feb; 18(8):e2107186. PubMed ID: 35092137.
    Abstract:
    The potassium-ion battery (PIB) is an emerging energy storage technology due to its potential low cost and reasonably high energy density. However, PIB suffers from severe potassium (K) dendrites growth and even short circuiting caused by the high reactivity of K metal. To address these challenges, this work develops a robust composite gel polymer electrolyte (CGPE), named poly(vinylidene fluoride-hexafluoropropylene) potassium bis(fluorosulfonyl)imide polyacrylonitrile (PVDF-HFP-KFSI@PAN). It is found that the introduction of PAN nanofibers not only improves the mechanical properties but also widens the electrochemical stability window of the CGPE. As a result, the CGPE is much more effective in regulating K stripping/plating and enabling stable K metal anode. K metal symmetrical cells with CGPE exhibit a lifetime of over 1200 h at the current density of 0.5 mA cm-2 , in contrast to 22 h for PVDF-HFP-KFSI and 185 h for a conventional glass fiber separator. The main reasons for the excellent performance of K metal cells with CGPE are attributed to the suppressed K dendrite growth, good structural integrity electrochemical stability of the CGPE, and stable KF-rich solid electrolyte interphase layer at the electrode-CGPE interface. It is expected that this facile strategy to stabilize K metal will pave the way for safer and more durable K metal batteries.
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