These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Enantioselective evaluation of the chiral fungicide mandipropamid: Dissipation, distribution and potential dietary intake risk in tomato, cucumber, Chinese cabbage and cowpea.
    Author: Li J, Lan T, Yang G, Mu S, Zhang K.
    Journal: Ecotoxicol Environ Saf; 2022 Mar 01; 232():113260. PubMed ID: 35121257.
    Abstract:
    A chiral analytical method was developed and validated for the determination of mandipropamid enantiomers in tomato, cucumber, Chinese cabbage and cowpea. The linearity (R2 > 0.99), accuracy (recovery: 73.8-106%) and precision (relative standard deviation: < 11%) were adequate for the detection of mandipropamid enantiomers in four vegetables. Field trials were further conducted to investigate the dissipation and residue distribution of mandipropamid and the possible enantioselectivity in different vegetables. Due to the shorter half-lives, mandipropamid dissipated more rapidly in Chinese cabbage (1.8-2.0 d) and cowpea (1.6-2.4 d) than in tomato (5.0-8.4 d) and cucumber (2.4-5.5 d). The residues of mandipropamid were 45-179 µg/kg in tomato 14 d at low dose, 48-98 µg/kg in cucumber 7 d after spraying twice at low dose, and < 2.5-1942 µg/kg in Chinese cabbage and cowpea in all treatments, which were below the maximum residue limits of mandipropamid set by the European Union and Codex Alimentarius Commission. Enantioselectivity was observed during the mandipropamid dissipation process in four vegetables. The S-(+)-enantiomer dissipated more rapidly than the R-(-)-enantiomer in tomato and Chinese cabbage (enantiomeric fractions > 0.5). For cucumber and cowpea, the dissipation of the R-enantiomer was preferential (enantiomeric fractions < 0.5). According to the risk quotient data (<< 100%), the residues of mandipropamid in four vegetables were safe for Chinese consumers. This study could provide useful information for the dissipation fate and residue distribution of mandipropamid in vegetables at the enantiomer level and offer some guidance for the dietary intake risk evaluation of mandipropamid in vegetables.
    [Abstract] [Full Text] [Related] [New Search]