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  • Title: Efficient monolithic MnOx catalyst prepared by heat treatment for ozone decomposition.
    Author: Qiu J, Wang W, Wang J, Zhao M, Chen Y.
    Journal: Environ Sci Pollut Res Int; 2022 Jun; 29(29):44324-44334. PubMed ID: 35129750.
    Abstract:
    The effects of calcined temperature on the properties and ozone decomposition activity of manganese oxide catalysts were investigated under high-humidity, low ozone conditions. An outstanding manganese-based catalyst (MnOx (260 ℃)) was prepared, which could decompose above 90% (RH = 0%) and 70% (RH = 90%) ozone after 6 h using. Specific characterization showed MnOx (260 ℃) had excellent properties. XRD results showed MnOx (260 ℃) was mainly Mn3O4 and partially MnO2. TEM indicated MnOx (260 ℃) exposed highly active crystal family plan MnO2 (110), and the lattice fringes of MnO2 (110) and Mn3O4 (103) overlapped. In situ DRIFT showed hydroxyl groups adsorbed on MnOx (260 ℃) were removed, which is beneficial to inhibiting the inactivation caused by surface water accumulation. O2-TPD results proven MnOx (260 ℃) had good oxygen migration ability. XPS results manifested that MnOx (260 ℃) had the most adsorbed oxygen. In short, when the calcination temperature is appropriate, MnOx (260 ℃) has coexisted multiple phases, exposed high active crystal family plan and removed surface hydroxyl, which is conducive to the exposure of oxygen vacancies and the inhibition of deactivation.
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