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  • Title: Deoxygenative C-S Bond Coupling with Sulfinates via Nickel/Photoredox Dual Catalysis.
    Author: Zhong S, Zhou Z, Zhao F, Mao G, Deng GJ, Huang H.
    Journal: Org Lett; 2022 Mar 11; 24(9):1865-1870. PubMed ID: 35225630.
    Abstract:
    The C-S bond formation from aryl halides and thiols has been well established under various catalytic systems. In this work, user-friendly sulfinates have been exploited as an efficient sulfenylating reagent in the C-S couplings through visible-light-induced photo/nickel dual catalysis under base- and external reductant-free conditions. A large number of aryl sulfide products were accessed with high selectivity and high tolerance of various functionalities.
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