These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Lithium Nafion-Modified Li6.05Ga0.25La3Zr2O11.8F0.2 Trilayer Hybrid Solid Electrolyte for High-Voltage Cathodes in All-Solid-State Lithium-Metal Batteries.
    Author: Walle KZ, Wu YS, Wu SH, Chang JK, Jose R, Yang CC.
    Journal: ACS Appl Mater Interfaces; 2022 Apr 06; 14(13):15259-15274. PubMed ID: 35344344.
    Abstract:
    All-solid-state batteries containing ceramic-polymer solid electrolytes are possible alternatives to lithium-metal batteries containing liquid electrolytes in terms of their safety, energy storage, and stability at elevated temperatures. In this study we prepared a garnet-type Li6.05Ga0.25La3Zr2O11.8F0.2 (LGLZOF) solid electrolyte modified with lithium Nafion (LiNf) and incorporated it into poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) matrixes. We used a solution-casting method to obtain bilayer (Bi-HSE) and trilayer (Tri-HSE) hybrid solid electrolytes. A layer of functionalized multiwalled carbon nanotubes (f-MWCNTs) coated with LiNf (LiNf@f-MWCNT) in the Tri-HSE led to good compatibility with the polymer slurry and adhered well to the Li anode, thereby improving the interfacial contact at the electrode-solid electrolyte interface and suppressing dendrite growth. The Tri-HSE membrane displayed high ionic conductivity (5.6 × 10-4 S cm-1 at 30 °C), a superior Li+ transference number (0.87), and a wide electrochemical window (0-5.0 V vs Li/Li+). In addition, Li symmetrical cells incorporating this hybrid electrolyte possessed excellent interfacial stability over 600 h at 0.1 mA cm-2 and a high critical current density (1.5 mA cm-2). Solid-state lithium batteries having the structure LiNf@LiNi0.8Co0.1Mn0.1O2/Tri-HSE/Li delivered excellent room-temperature stable cycling performance at 0.5C, with a capacity retention of 85.1% after 450 cycles.
    [Abstract] [Full Text] [Related] [New Search]