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  • Title: Kill two birds with one stone: Selective and fast removal and sensitive determination of oxytetracycline using surface molecularly imprinted polymer based on ionic liquid and ATRP polymerization.
    Author: Chen Y, Tang Y, Liu Y, Zhao F, Zeng B.
    Journal: J Hazard Mater; 2022 Jul 15; 434():128907. PubMed ID: 35452985.
    Abstract:
    Oxytetracycline (OTC) residue in food and environment has potential threats to ecosystem and human health, thus its sensitive monitoring and effective elimination are very important. In this work, a new molecularly imprinted polymer (MIP) composite was prepared through atom transfer radical polymerization by using OTC as template, gold nanoparticles modified carbon nanospheres (Au-CNS) as supporter, ionic liquids (IL) as functional monomer and cross-linking agent. The obtained MIP-IL@Au-CNS composite was characterized by Fourier transform infrared absorption spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy and transmission electron microscopy. It displayed high imprinting factor (5.50) and adsorption capacity (56.7 mg g-1), and could achieved the adsorption equilibrium in short time (about 15 min). Results also illustrated that the adsorption process basically conformed to the quasi-second-order kinetic model and Freundlich model, and MIP-IL@Au-CNS could be recycled at least 5 times. Furthermore, a sensitive OTC electrochemical sensor was developed by combining MIP-IL@Au-CNS with IL-modified carbon nanocomposites (IL@N-rGO-MWCNT). The resulting sensor demonstrated a linear response to OTC in the wide range of 0.02-20 μM, and the detection limit was down to 5 nM. It also had the advantages of high selectivity, fast elution/regeneration and simple construction procedure. The sensor had been applied to the detection of real samples, and acceptable recovery (96.4%-106%) and RSD (3.2%-6.2%) were obtained. This work expands the application of IL-based MIP in pollutant monitoring and enriching.
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