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  • Title: Epitaxial synthesis of Ni-MoS2/Ti3C2T x MXene heterostructures for hydrodesulfurization.
    Author: Vinoba M, Navvamani R, Al-Sheeha H.
    Journal: RSC Adv; 2020 Mar 24; 10(21):12308-12317. PubMed ID: 35497617.
    Abstract:
    Hierarchical structures of 2D layered Ti3C2T x MXene hold potential for a range of applications. In this study, catalysts comprising few-layered MoS2 with Ti3C2T x have been formulated for hydrodesulfurization (HDS). The support Ti3C2T x was derived from MAX phases (Ti3AlC2) via a liquid-phase exfoliation process, while MoS2 was obtained from synthesized aqueous ammonium tetrathiomolybdate (ATM). Furthermore, a series of catalysts with different architectures was synthesized by confinement of ATM and/or the promoter Ni in Ti3C2T x at different mole ratios, through a thermal conversion process. The synthesized MoS2/Ti3C2T x and Ni-MoS2/Ti3C2T x catalysts were characterized using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDS), high-resolution transmission electron microscopy (HRTEM), and temperature-programmed reduction (TPR) measurements. The number of MoS2 layers formed on the Ti3C2T x support was calculated using Raman spectroscopy. The heterostructured few-layered MoS2/Ti3C2T x catalysts were applied in sulfur removal efficiency experiments involving thiophene. The active MoS2 sites confined by the Ti3C2T x enhanced hydrogen activation by proton saturation, and the electron charge stabilized the sulfur atom to facilitate hydrogenation reactions, leading to predominant formation of C4 hydrocarbons. The Ni-MoS2/Ti3C2T x showed the best activity at a promoter molar ratio of 0.3 when compared to the other catalysts. In particular, it is evident from the results that ATM and Ti3C2T x are potential materials for the in situ fabrication of hierarchical few-layered MoS2/Ti3C2T x catalysts for enhancing hydrodesulfurization activity in clean fuel production.
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