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  • Title: An organic-inorganic hybrid nanomaterial composed of a Dowson-type (NH4)6P2Mo18O62 heteropolyanion and a metal-organic framework: synthesis, characterization, and application as an effective adsorbent for the removal of organic dyes.
    Author: Hoseini AA, Farhadi S, Zabardasti A, Siadatnasab F.
    Journal: RSC Adv; 2020 Nov 02; 10(66):40005-40018. PubMed ID: 35520823.
    Abstract:
    In this work, an inorganic-organic hybrid nanomaterial, P2Mo18/MIL-101(Cr), based on Wells-Dawson-type (NH4)6P2Mo18O62 polyoxometalate (abbreviated as P2Mo18) and the MIL-101(Cr) metal-organic framework was fabricated by the reaction of (NH4)6P2Mo18O62, Cr(NO3)3·9H2O and terephthalic acid under hydrothermal conditions. The as-prepared recyclable nanohybrid was fully characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR) equipped with energy dispersive X-ray microanalysis (EDX), field emission scanning electron microscopy (FE-SEM), Raman spectroscopy and Brunauer-Emmett-Teller (BET) specific surface area studies. All the analyses confirmed the successful insertion of P2Mo18O62 6- heteropolyanion within the cavities of MIL-101(Cr). The encapsulated MIL-101(Cr) showed a considerable decrease in both pore volume and surface area compared with MIL-101(Cr) due to incorporation of the very large Dowson-type polyoxometalate into the three-dimensional porous MIL-101(Cr). The nanohybrid had a specific surface area of 800.42 m2 g-1. The adsorption efficiency of this nanohybrid for removal of methylene blue (MB), rhodamine B (RhB), and methyl orange (MO) from aqueous solutions was evaluated. Surprisingly, the composite not only presented a high adsorption capacity of 312.5 mg g-1 for MB, but also has the ability to rapidly remove 100% MB from a dye solution of 50 mg L-1 within 3 min. These results confirmed that this adsorbent is applicable in a wide pH range of 2-10. The nanohybrid showed rapid and selective adsorption for cationic MB and RhB dyes from MB/MO, MB/RhB, MO/RhB and MB/MO/RhB mixed dye solutions. The equilibrium adsorption data were better fitted by the Langmuir isotherm. Kinetics data indicate that the adsorption of the dye follows a pseudo-second order kinetics model. Also, this material could be effortlessly separated and recycled without any structural modification. Accordingly, it is an efficient adsorbent for removing cationic dyes.
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