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  • Title: Nickel/Photoredox-Catalyzed Enantioselective Reductive Cross-Coupling between Vinyl Bromides and Benzyl Chlorides.
    Author: Lu Q, Guan H, Wang YE, Xiong D, Lin T, Xue F, Mao J.
    Journal: J Org Chem; 2022 Jun 17; 87(12):8048-8058. PubMed ID: 35666844.
    Abstract:
    A visible-light-promoted nickel/photoredox-catalyzed reductive cross-coupling reaction between vinyl bromides and benzyl chlorides is reported. A diverse array of enantioenriched allylic centers containing products could be achieved in good yields (up to 90%) and high enantioselectivities (up to 95% ee). The mechanistic studies show that this reductive cross-coupling involves a radical pathway.
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