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  • Title: Visible-light-induced defluorinative carbonylative coupling of alkyl iodides with α-trifluoromethyl substituted styrenes.
    Author: Chen B, Yu K, Wu XF.
    Journal: Org Biomol Chem; 2022 Jul 06; 20(26):5264-5269. PubMed ID: 35723274.
    Abstract:
    A visible-light-mediated defluorinative carbonylative cross-coupling of alkyl iodides with α-trifluoromethyl styrenes has been developed. The reaction occurs at room temperature under blue light irradiation, and various gem-difluoroalkenes were obtained in moderate to good yields. Synthetic transformations of the obtained product were performed as well.
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