These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Atomically Reconstructed Palladium Metallene by Intercalation-Induced Lattice Expansion and Amorphization for Highly Efficient Electrocatalysis.
    Author: Xie M, Zhang B, Jin Z, Li P, Yu G.
    Journal: ACS Nano; 2022 Sep 27; 16(9):13715-13727. PubMed ID: 35947035.
    Abstract:
    As an emerging class of materials with distinctive physicochemical properties, metallenes are deemed as efficient catalysts for energy-related electrocatalytic reactions. Engineering the lattice strain, electronic structure, crystallinity, and even surface porosity of metallene provides a great opportunity to further enhance its catalytic performance. Herein, we rationally developed a reconstruction strategy of Pd metallenes at atomic scale to generate a series of nonmetallic atom-intercalated Pd metallenes (M-Pdene, M = H, N, C) with lattice expansion and S-doped Pd metallene (S-Pdene) with an amorphous structure. Catalytic performance evaluation demonstrated that N-Pdene exhibited the highest mass activities of 7.96 A mg-1, which was 10.6 and 8.5 time greater than those of commercial Pd/C and Pt/C, respectively, for methanol oxidation reaction (MOR). Density functional theory calculations suggested that the well-controlled lattice tensile strain as well as the strong p-d hybridization interaction between N and Pd resulted in enhanced OH adsorption and weakened CO adsorption for efficient MOR catalysis on N-Pdene. When tested as hydrogen evolution reaction (HER) catalysts, the amorphous S-Pdene delivered superior activity and durability relative to the crystalline counterparts because of the disordered Pd surface with a further elongated bond length and a downshifted d-band center. This work provides an effective strategy for atomic engineering of metallene nanomaterials with high performance as electrocatalysts.
    [Abstract] [Full Text] [Related] [New Search]