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  • Title: Ultrasonic-assisted preparation of interlaced layered hydrotalcite (U-Fe/Al-LDH) for high-efficiency removal of Cr(VI): Enhancing adsorption-coupled reduction capacity and stability.
    Author: Tan X, Zhang Y, Liu M, Cao J, Duan G, Cui J, Lin A.
    Journal: Chemosphere; 2022 Dec; 308(Pt 3):136472. PubMed ID: 36122742.
    Abstract:
    Cr(VI) contamination in aquatic systems has been a challenge for environmental science researchers. To environmental-friendly, stable, and efficiently remove Cr (VI), a novel layered double hydroxide was prepared through the ultrasonic-assisted co-precipitation method. The ultrasonic-assisted step prevented the Fe2+ oxidation, improved the morphology and performance, and finally, the adsorption-coupled reduction capacity and stability were enhanced. By adding U-Fe/Al-LDH (1.0 g/L) for Cr(VI) (100 mg/L), the removal rate reached 82.24%. The removal data were well fitted by the pseudo-second-order kinetic and Langmuir isotherm model. Using U-Fe/Al-LDH can be performed over a wide pH range (2-10), with a theoretical maximum removal capacity of 118.65 mg/g. The Cr(VI) with high toxicity was adsorbed and reduced to low-toxicity Cr(III). In the final phase, stable Cr(III) complex precipitates were generated. After 30 days, the dynamic leaching amounts of total Cr in used U-Fe/Al-LDH-2 were 0.1052 mg/L. Combined with the results of the influence experiment of coexisting anions and oxidants and the SO42- release experiment, the stability of the removal effect and the safety of U-Fe/Al-LDH were proved. In conclusion, U-Fe/Al-LDH-2 is a promising remediation agent and a feasible Cr(VI) removal method for the practical remediation.
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