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  • Title: Construction of Bimetallic Metal-Organic Frameworks with the Nanosheet-Assembled Hierarchical Hollow Structure for CO2 Fixation.
    Author: Chen H, Shao L, Zhai X, Fu Y.
    Journal: Inorg Chem; 2022 Oct 03; 61(39):15416-15422. PubMed ID: 36136375.
    Abstract:
    Incorporating secondary metal nodes with functionality into organic ligand nodes to form a bimetallic metal-organic frameworks (MOFs) would facilitate an enhancement in properties and broaden applied areas of MOFs. Hierarchical tubular Cu/Zn-MOF-74 assembled by nanosheet arrays is synthesized at ambient temperature and pressure by phase transformation of Cu-based precursor MOF in immersion solution with Zn2+. The content of Zn in Cu/Zn-MOF-74 can be controlled by adjusting the concentration of Zn2+ in immersion solution, and it can reach a maximum of 36.4%. Moreover, the catalytic activity toward cycloaddition of CO2 with styrene oxide of Cu/Zn-MOF-74 is improved significantly compared with that of monometallic Cu-MOF-74. Meanwhile, the advanced hierarchical tubular structure contributing to enhancement in catalytic activity enables Cu/Zn-MOF-74 to present higher conversion toward this cycloaddition of CO2 than traditional rod-like Cu/Zn-MOF-74. This templated synthesis would provide an opportunity for designing various bimetallic MOFs or MOF-based compounds with improved performances in multiple applications.
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