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  • Title: Enhancement of the Electrochemical Performances of Composite Solid-State Electrolytes by Doping with Graphene.
    Author: Liang X, Huang D, Lan L, Yang G, Huang J.
    Journal: Nanomaterials (Basel); 2022 Sep 16; 12(18):. PubMed ID: 36145004.
    Abstract:
    With high safety and good flexibility, polymer-based composite solid electrolytes are considered to be promising electrolytes and are widely investigated in solid lithium batteries. However, the low conductivity and high interfacial impedance of polymer-based solid electrolytes hinder their industrial applications. Herein, a composite solid-state electrolyte containing graphene (PVDF-LATP-LiClO4-Graphene) with structurally stable and good electrochemical performance is explored and enables excellent electrochemical properties for lithium-ion batteries. The ionic conductivity of the composite electrolyte membrane containing 5 wt% graphene reaches 2.00 × 10-3 S cm-1 at 25 °C, which is higher than that of the composite electrolyte membrane without graphene (2.67 × 10-4 S cm-1). The electrochemical window of the composite electrolyte membrane containing 5 wt% graphene reaches 4.6 V, and its Li+ transference numbers reach 0.84. Assembling this electrolyte into the battery, the LFP/PVDF-LATP-LiClO4-Graphene /Li battery has a specific discharge capacity of 107 mAh g-1 at 0.2 C, and the capacity retention rate was 91.58% after 100 cycles, higher than that of the LiFePO4/PVDF-LATP-LiClO4/Li (LFP/PLL/Li) battery, being 94 mAh g-1 and 89.36%, respectively. This work provides a feasible solution for the potential application of composite solid electrolytes.
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