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  • Title: Protoboration of Alkynes and Miyaura Borylation Catalyzed by Low Loadings of Palladium.
    Author: Xu L, Dong Z, Zhang Q, Deng N, Li SY, Xu HJ.
    Journal: J Org Chem; 2022 Nov 04; 87(21):14879-14888. PubMed ID: 36223839.
    Abstract:
    The versions of Miyaura borylation and protoboration of alkynes catalyzed by low loadings of palladium (400 mol ppm = 0.04 mol %) have been developed. These transformations have a broad substrate scope, good functional-group compatibility, and gram-scale synthetic ability.
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