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  • Title: Copper catalysed protoboration of allenyl-Bdans: efficient synthesis of β-boryl allyl-Bdans.
    Author: Li SS, Zhong Q, Zhao J.
    Journal: Org Biomol Chem; 2022 Nov 16; 20(44):8605-8609. PubMed ID: 36300376.
    Abstract:
    An efficient Cu-catalysed protoboration of allenyl-Bdans is presented. Under the optimized reaction conditions, a series of allenyl-Bdans reacted smoothly with B2Pin2 to afford β-boryl allyl-Bdans in moderate to high yields with excellent regio- and stereoselectivity.
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