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  • Title: Crosslinked poly (vinyl alcohol) composite reinforced with tunicate, wood, and hybrid cellulose nanocrystals: Comparative physicochemical, thermal, and mechanical properties.
    Author: Babaei-Ghazvini A, Acharya B.
    Journal: Int J Biol Macromol; 2023 Feb 01; 227():1048-1058. PubMed ID: 36460242.
    Abstract:
    The development of sustainable and biodegradable composites has gained increasing attention in recent years. Effective interaction and adhesion between polymers and fillers are crucial. In this study, the effect of different aspect ratios of cellulose nanocrystals (CNCs) and their hybrid within a crosslinked poly (vinyl alcohol) (PVA) nanocomposite has been investigated to develop biodegradable materials. The physicochemical, thermal, and mechanical properties of the specimens have been studied. SEM images indicate that the addition of CNC reduced the porosity of the films. The XPS results confirmed the significant formation of covalent bonds for all composites except those reinforced with wood-CNC, which showed a lower amount of crosslinking and CC formation. EDS maps reveals that the dispersity of the CNCs could be different depending on the aspect ratio of the CNCs. Results from the solubility in water (SW) tests indicated that the use of hybrid-CNC in a crosslinked system decreased the SW significantly. The crosslinking and addition of CNC to the PVA composite led to improved mechanical properties. Elongation at break (EB) decreased significantly for the crosslinked hybrid-CNC nanocomposite. Overall, the results of this study indicate that the aspect ratio of CNCs as fillers in nanocomposites may contribute to their physicochemical, mechanical, and thermal properties for the development of biodegradable materials.
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