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  • Title: Fabrication of hybrid covalent triazine framework-zinc ferrite spinel to uplift visible light-driven photocatalytic organic pollutant degradation.
    Author: Saputra E, Prawiranegara BA, Nugraha MW, Sambudi NS, Sugesti H, Awaluddin A, Komalasari, Utama PS, Manawan M.
    Journal: Environ Sci Pollut Res Int; 2023 Mar; 30(14):39961-39977. PubMed ID: 36602743.
    Abstract:
    The tunability of porous covalent triazine frameworks (CTFs) can mitigate poor photostability and rapid hole-electron recombination. Herein, an excellent improvement of visible light-driven photocatalytic pollutant degradation was achieved using a hybrid semiconductor of covalent triazine framework-zinc ferrite spinel catalysts (CTF-ZnFe2O4). The as-prepared CTF-ZnFe2O4 composites were fabricated using a facile one-pot ionothermal method. The hybrid photocatalysts were identified using X-ray diffraction (XRD), scanning electron microscopy/energy-dispersive X-ray (SEM-EDX), X-ray photoelectron spectrometer (XPS), Brunauer-Emmett-Teller (BET), Fourier transform infrared (FTIR), and UV-visible diffuse reflection spectroscopy (UV-vis DRS) characterizations. The analysis reveals that hybridization successfully ensued and altered the crystallinity structure, morphology, surface area, and bandgap energy of hybrid material. It was found that CTF-ZnFe2O4 90:10 is very effective for the degradation of MB in a UV-vis light photocatalytic process with the efficiency of 95.4% and kobs of 0.421 min-1 for degradation of 50 mg/L MB with 0.5 g/L dosages for 120 min. Additionally, the scavenger study, effect of additional oxidants, and stability were performed for the practical application of a hybrid photocatalyst. CTF-ZnFe2O4 90:10 shows outstanding pollutant degradation in sunlight irradiation and high stability with only a 5.2% reduction after a five-times sequential recycling process. Moreover, the photocatalytic mechanism of as-prepared CTF-ZnFe2O4 was mainly influenced by [Formula: see text] radical compared to [Formula: see text] and [Formula: see text] radicals. Overall, The as-prepared CTF-ZnFe2O4 shows significant potential to be utilized for photocatalytic wastewater treatment.
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