These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.
Pubmed for Handhelds
PUBMED FOR HANDHELDS
Search MEDLINE/PubMed
Title: Removal of pharmaceutically active compounds from water sources using nanofiltration and reverse osmosis membranes: Comparison of removal efficiencies and in-depth analysis of rejection mechanisms. Author: Matin A, Jillani SMS, Baig U, Ihsanullah I, Alhooshani K. Journal: J Environ Manage; 2023 Jul 15; 338():117682. PubMed ID: 37003228. Abstract: Trace organic compounds from effluent streams are not completely removed by conventional purification techniques and hence, contaminating groundwater sources. Herein, we report the removal efficiency and rejection mechanisms of three common pharmaceutically active compounds (PhACs); caffeine (CFN), omeprazole (OMZ), and sulfamethoxazole (SMX), using commercial nanofiltration (NF) and reverse osmosis (RO) membranes with different surface characteristics. The RO membranes showed near-complete removal of all PhACs with rejection rates >99%. On the other hand, retention capabilities for the NF membranes varied and were influenced by the characteristics of the PhACs, membranes, and the feed solution. In general, during long-term testing, the rejection did not show much variation and followed a trend compatible with the size exclusion (steric hindrance) mechanism. When a real matrix was used, the rejection of CFN by the more tight NF membranes, HL TFC and NFW decreased by ∼10%, whereas the removal of SMX by the loose NF membrane, XN45, increased by the same ratio. In short-term testing, the rejection of negatively charged SMX increased significantly (∼20-40%) at a higher pH of ∼8 and in the presence of salts. Fouling by the PhACs was more severe on the high-flux NF membranes, HL TFC and XN45, as witnessed by the significant change in Contact angle (CA) values (∼25-50°) as well as the flux decline (∼15%) during long-term testing. To summarize, the removal of PhACs by membranes is a complex phenomenon and depends upon a combination of several factors.[Abstract] [Full Text] [Related] [New Search]