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  • Title: Investigation on removal of multi-component volatile organic compounds in a two-stage plasma catalytic oxidation system - Comparison of X (X=Cu, Fe, Ce and La) doped Mn2O3 catalysts.
    Author: Liu X, Liu J, Chen J, Zhong F.
    Journal: Chemosphere; 2023 Jul; 329():138557. PubMed ID: 37037354.
    Abstract:
    Mn2O3-X catalysts (X = Cu, Fe, Ce and La) were prepared based on γ-Al2O3 for the mixture degradation of muti-component volatile organic compounds (VOCs) composed of toluene, acetone, and ethyl acetate. The catalysts were characterized, and the density functional theory (DFT) simulation of ozone adsorption on Mn2O3-X were carried out to investigate the influence of adsorption energy on catalytic performance. The results showed that the removal efficiency (RE) of each VOC component was similarly improved by Mn2O3-X catalysts, and the greatest increase in VOCs' removal efficiency was obtained (7.8% for toluene, 86.2% for acetone, and 82.5% for ethyl acetate) at a special input energy (SIE) of 700 J L-1 with Mn2O3-La catalyst. Characterization results demonstrated that Mn2O3-La catalyst had the highest content of low valence Mn elements and the greatest Oads/Olatt ratio, as well as the lowest reduction temperature. Mn2O3-La catalyst also presented superior catalytic effect in improving carbon balance (CB) and CO2 selectivity ( [Formula: see text] ). The CB and [Formula: see text] were increased by 47.7% and 12.61% respectively with Mn2O3-La at a SIE of 400 J L-1 compared with that when only γ-Al2O3 was applied. The DFT simulation results of ozone adsorption on Mn2O3-X catalysts indicated that the adsorption energy of catalyst crystal was related to the catalytic performance of the catalyst. The Mn2O3-La/γ-Al2O3 catalyst, which had the highest absolute value of adsorption energy, presented the best performance in improving VOCs' RE.
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