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  • Title: Remote Electronic Effect of Chiral N-Heterocyclic Carbene Catalyst on an Asymmetric Benzoin Reaction.
    Author: Inokuma T, Hashimoto K, Fujiwara T, Sun C, Kuwano S, Yamada KI.
    Journal: Chemistry; 2023 Jul 06; 29(38):e202300858. PubMed ID: 37067457.
    Abstract:
    A remote electronic effect of chiral aminoindanol-derived N-heterocyclic carbene catalyst on an asymmetric benzoin reaction was investigated. The catalyst bearing remote electron-withdrawing substituents increased enantioselectivity of the reaction at the cost of the reaction rate. DFT calculations rationalized the increased enantioselectivity.
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