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  • Title: Chromium-Catalyzed Three-Component Synthesis of Monofluoroalkenes from gem-Difluoroalkenes via C-O/C-H and C-F Bond Activation.
    Author: Xiong Y, Luo M, Zeng X.
    Journal: Org Lett; 2023 May 05; 25(17):3120-3125. PubMed ID: 37098850.
    Abstract:
    We report here the chromium-catalyzed three-component defluorinative cross-couplings of gem-difluoroalkenes with benzyl 2-pyridinyl ethers and aryl Grignard reagents under mild conditions, enabling the convenient synthesis of diarylmethylated monofluoroalkenes in good chemo- and stereoselectivity.
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