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  • Title: Nickel-catalyzed stereoselective reductive cross-coupling of gem-difluoroalkenes with alkenyl electrophiles.
    Author: Li X, Li Y, Shan W, Wang Z, Liu R, Zhang Z, Li X, Shi D.
    Journal: Chem Commun (Camb); 2023 Jun 01; 59(45):6893-6896. PubMed ID: 37199088.
    Abstract:
    Herein we develop a Ni-catalyzed defluorinative cross-electrophile coupling of gem-difluoroalkenes with alkenyl electrophiles that allowed the generation of C(sp2)-C(sp2) bonds. The reaction provided various monofluoro 1,3-dienes with broad functional group compatibility and excellent stereoselectivity. Synthetic transformations and applications to the modification of complex compounds were also demonstrated.
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