These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Highly compressible and hydrophobic nanofibrillated cellulose aerogels for cyclic oil/water separation.
    Author: Fan B, Wu L, Ming A, Liu Y, Yu Y, Cui L, Zhou M, Wang Q, Wang P.
    Journal: Int J Biol Macromol; 2023 Jul 01; 242(Pt 3):125066. PubMed ID: 37268071.
    Abstract:
    Nanofibrillated cellulose (NFC)-based aerogels are ideal oil-sorbent materials, but the poor structural stability and hydrophilicity restrain their practical applications in the fields of oil/water separation. In the present work, we report a facile strategy for constructing a hydrophobic nanofibrillated cellulose aerogel for cyclic oil/water separation. Briefly, an aerogel matrix of C-g-PEI with multiple cross-linked network structures was constructed via the combined use of oxidized-NFC (ONC), polyethyleneimine (PEI), and ethylene glycol diglycidyl ether (EGDE), followed by rapid in situ deposition of poly(methyl trichlorosilane) (PMTS) through a low-temperature gas-solid reaction. The resulting ONC-based aerogel (C-g-PEI-PMTS) exhibits the advantages of ultralight (53.80 mg/cm3), high porosity (95.73 %), hydrophobicity (contact angle of 130.0°) and remarkable elasticity (95.86 %). Meanwhile, the composite aerogel of C-g-PEI-PMTS is extremely suitable for oil sorption-desorption by a simple mechanical squeezing method. After 10 cycles of sorption-desorption, the sorption capacity of the aerogel towards various oils reached almost the same level as in the first cycle. The filtration separation efficiency for the trichloromethane-water mixtures remained at 99 % after 50 cycles, demonstrating encouraging reusability. In summary, an efficient strategy to prepare NFC-based aerogel with highly compressible and hydrophobic properties is developed, which expands the applications of NFC in the fields of oil/water separation.
    [Abstract] [Full Text] [Related] [New Search]