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Title: Single-Ion Polymer Electrolyte Based on Lithium-Rich Imidazole Anionic Porous Aromatic Framework for High Performance Lithium-Ion Batteries.
Author: Li Z, Wang L, Liu Y, Yu M, Liu B, Men Y, Sun Z, Hu W, Zhu G.
Journal: Small; 2023 Oct; 19(41):e2302818. PubMed ID: 37283476.
Abstract:
The low ionic conductivity and Li⁺ transference number ( t L i + ${t}_{L{i}^ + }$ ) of solid polymer electrolytes (SPEs) seriously hinder their application in lithium-ion batteries (LIBs). In this study, a novel single-ion lithium-rich imidazole anionic porous aromatic framework (PAF-220-Li) is designed. The abundant pores in PAF-220-Li are conducive to the Li⁺ transfer. Imidazole anion has low binding force with Li⁺ . The conjugation of imidazole and benzene ring can further reduce the binding energy between Li⁺ and anions. Thus, only Li⁺ moved freely in the SPEs, remarkably reducing the concentration polarization and inhibiting lithium dendrite growth. PAF-220-quasi-solid polymer electrolyte (PAF-220-QSPE) is prepared through solution casting of Bis(trifluoromethane)sulfonimide lithium (LiTFSI) infused PAF-220-Li and Poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP), and possessed excellent electrochemical performance. The electrochemical property are further improved by preparing all-solid polymer electrolyte (PAF-220-ASPE) via pressing-disc method, which has a high Li⁺ conductivity of 0.501 mS cm^-1 and t L i + ${t}_{L{i}^ + }$ of 0.93. The discharge specific capacity at 0.2 C of Li//PAF-220-ASPE//LFP reached 164 mAh g^-1 , and the capacity retention rate is 90% after 180 cycles. This study provided a promising strategy for SPE with single-ion PAFs to achieve high-performance solid-state LIBs.

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