These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Green Nanocellulose/PEI-Grafted Magnetic Nanoparticles for Effective Removal of Heavy Metal Ions.
    Author: Sathasivam T, Kang Brian L, Andersen IM, Ru Tan H, Zhang Z, Wu T, Hong Lau H, Zhu Q, Kai D.
    Journal: Chem Asian J; 2023 Dec 14; 18(24):e202300842. PubMed ID: 37903723.
    Abstract:
    In response to the pressing issue of water pollution caused by heavy metal ions, there is a growing demand for green adsorbents that can effectively remove these contaminants while being easy to separate and regenerate. A novel magnetic composite was synthesized by bonding amino-functionalized Fe3 O4 -SiO2 magnetic particles (MNP-NH2 ) to polyethyleneimine (PEI)-grafted cellulose nanofibers (CNF). The modification of CNF with PEI through a peptidic coupling reaction resulted in the uniform dispersion and strong attachment of MNP-NH2 particles (286.7 nm) onto the PEI-CNF surface. This composite exhibited exceptional adsorption capabilities for heavy metals, achieving 16.73 mg/g for Pb, 16.12 mg/g for Cu, and 12.53 mg/g for Co. These remarkable adsorption capacities are attributed to the complex interactions between the metal ions and the amino, carboxyl, and hydroxyl groups on the surface of PEI-CNF-MNP. The introduction of PEI significantly enhanced the adsorption capacities, and the adsorption sequence (Pb(II)>Cu(II)>Co(II)) can be explained by differences in ionic radius and surface complexation strength. Langmuir isotherm and pseudo-second-order kinetic models described the adsorption process, while Na2 EDTA was proved effective for desorption with high recovery rates. This magnetic composite holds promise for treating heavy metal-contaminated wastewater due to its impressive performance.
    [Abstract] [Full Text] [Related] [New Search]