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  • Title: Fabrication of Iron-Containing Biochar by One-Step Ball Milling for Cr(VI) and Tetracycline Removal from Wastewater.
    Author: Jiang F, Wei C, Yu Z, Ji L, Liu M, Cao Q, Wu L, Li F.
    Journal: Langmuir; 2023 Dec 26; 39(51):18958-18970. PubMed ID: 38095154.
    Abstract:
    Simple ball milling technology can simultaneously improve the adsorption performance of adsorbents for heavy metals and organic pollutants and has attracted increasing attention. Iron-modified biochar (Fe@MBC) was prepared by one-step ball milling, and the characterization results proved that FeCl3 was successfully loaded on biochar. The removal rates of Cr(VI) and tetracycline hydrochloride (TC) by Fe@MBC were increased by 88.27% and 82.64% compared with BC. The average pore size, oxygen-containing functional groups and graphitization degree of Fe@MBC are higher than those of BC, which is more conducive to promoting adsorption. The adsorption isotherms show that the adsorption of Cr(VI) and TC on the Fe@MBC surface conforms to the Langmuir type of single-layer adsorption and the Freundlich model of multilayer adsorption, respectively. The maximum adsorption capacities of Cr(VI) and TC are 25.46 and 66.91 mg·g-1, respectively. Kinetic experiments show that the adsorption process is more consistent with the pseudo-second-order model of chemical adsorption. The adsorption process of Cr(VI) and TC on the Fe@MBC surface is a spontaneous endothermic process that becomes more obvious as the temperature increases. The increase in solution pH has a significant impact on the removal rate of Fe@MBC. When the pH value increased from 3 to 11, the adsorption rates decreased by 53.74% and 17.16%, respectively. The presence of PO43-, CO32-, K+, and Cu2+ significantly affects the adsorption of TC by Fe@MBC, and PO43- and CO32- also affect the adsorption of Cr(VI). Mechanistic studies show that ion exchange, electrostatic interaction, pore filling, and hydrogen bonding contribute to the removal of Cr(VI) and TC by Fe@MBC. The removal mechanism of Cr(VI) also involves complexation and redox reactions, and the removal mechanism of TC involves π-π bonds and van der Waals forces. The results show that Fe@MBC is a green and efficient adsorbent.
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