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  • Title: Synergistic activation of peroxymonosulfate by 3D CoNiO2/Co core-shell structure biochar catalyst for sulfamethoxazole degradation.
    Author: Liu Z, Shi X, Yan Z, Sun Z.
    Journal: Bioresour Technol; 2024 Aug; 406():130983. PubMed ID: 38880266.
    Abstract:
    In this study, a 3D CoNiO2/Co core-shell structure biochar catalyst derived from walnut shell was synthesized by hydrothermal and ion etching methods. The prepared BC@CoNi-600 catalyst exhibited exceptional peroxymonosulfate (PMS) activation. The system achieved 100 % degradation of sulfamethoxazole (SMX). The reactive oxygen species in the BC@CoNi-600/PMS system included SO4-, OH, and O2-. Density functional theory calculations explored the synergistic effects between nickel-cobalt bimetallic and carbon matrix during PMS activation. The unique 3D core-shell structure of BC@CoNi-600 features an outer nickel-cobalt bimetallic layer with exceptional PMS adsorption capacity, while protecting the zero-valence Co of the inner layer from oxidation. Based on the experimental-data, machine learning modeling mechanism, and information theory, a nonlinear modeling method was proposed. This study utilizes a machine learning approach to investigate the degradation of SMX in complex aquatic environments. This study synthesized a novel biochar-based catalyst for activated PMS and provided unique insights into its environmental applications.
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