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  • Title: Palladium-catalyzed site-selective functionalization of unactivated alkenes with vinylcyclopropanes aided by weakly coordinating native amides.
    Author: Keerthana MS, Jeganmohan M.
    Journal: Chem Commun (Camb); 2024 Jul 11; 60(57):7347-7350. PubMed ID: 38916280.
    Abstract:
    Herein, we have demonstrated a palladium-catalyzed regioselective allylation of unactivated alkenes with vinylcyclopropanes assisted by weak-coordinating native amides. The reaction exhibits wide substrate scope and excellent β-selectivity. Substrate diversification was performed to demonstrate the synthetic utility of the reaction. Mechanistic investigations were carried out to provide an insight into the reaction mechanism.
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