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  • Title: Dual magnetization and amination of cellulosic chains for the efficient adsorption of heavy metals.
    Author: Aminsharei F, Lahijanian A, Shiehbeigi A, Beiki SS, Ghashang M.
    Journal: Int J Biol Macromol; 2024 Sep; 276(Pt 2):134004. PubMed ID: 39032894.
    Abstract:
    Compounds functionalized with hydroxyl and amino groups were found to have good potential for the adsorption of different ions. In this work, a new system of cellulosic chains was amended with amine substitutions and bonded to a magnetic core of NiFe2O4@SiO2 to form NiFe2O4@SiO2-cellulose-NH2 system. The prepared sample showed suitable magnetic separation and was characterized via XRD, FT-IR, SEM, EDS, and TGA-DTA analyses. The adsorption potential of NiFe2O4@SiO2-cellulose-NH2 system has been investigated on the heavy metals (Cd, Ni, and Pb) removal from a synthetic wastewater environment. The results show that the magnetic property created by the magnetic core increased the recycling potential of the adsorbent and the magnetic core has a positive effect on the absorption potential of the polymer. The adsorption removal of Cd(II), Ni(II), and Pb(II) ions was studied using NiFe2O4@SiO2-cellulose-NH2 systems in different pH, temperatures, metal ion concentrations, and adsorbent dosages. The maximum adsorption capacities of single heavy metal ions were obtained as 406.44 mg/g (for Cd(II) ions), 411.63 mg/g (for Ni(II) ions), and 414.68 mg/g (for Pb(II) ions) under optimized conditions as pH = 6.5, ion concentration: 500 mg/L, adsorbent dosage: 1.2 g/L and room temperature.
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