These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Highly sensitive and highly selective lead ion electrochemical sensor based on zn/cu-btc-nh2 bimetallic MOFs with nano-reticulated reinforcing microstructure.
    Author: Qi T, Yuan Z, Meng F.
    Journal: Anal Chim Acta; 2024 Aug 22; 1318():342896. PubMed ID: 39067908.
    Abstract:
    Identifying ultra-trace amounts of divalent lead ions (Pb2+) with high response and selectivity, continues to be a pressing issue in identifying environmental pollutants and preventing health complications. This paper details how the in-situ electrodeposited Zn/Cu-BTC-NH2 metal-organic frameworks (MOFs) boosts Pb2+ concentration for amino adsorption and facilitates ion transfer between Cu element and Pb2+. The modified coating of the glassy carbon electrode (GCE) exhibits a unique nano-reticulated structure loaded with octahedron particles, the nano-reticulated structure ensures the structural strength of the modified electrode layer, while the loaded octahedral particles enhancing electrocatalytic activity. The ultra-trace detection of Pb2+ at concentrations below μg·L-1 is accomplished by using the square wave anodic stripping voltammetry (SWASV) method, the fabricated Zn/Cu-BTC-NH2 modified electrode signifies a detection threshold of 0.021 μg L-1 and a clearly ascending linear interval prior to the rise in Pb2+ concentration to 120 μg L-1. The reported electrochemical method for the precise identification of Pb2+ in water-based solutions offers a practical approach for modifying MOFs materials and detecting heavy metal ions.
    [Abstract] [Full Text] [Related] [New Search]