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  • Title: Examining the Interplay of Hydrolysed Polyacrylamide and Sodium Dodecyl Sulfate on Emulsion Stability: Insights from Turbiscan and Electrocoalescence Studies.
    Author: Painuly R, Anand V.
    Journal: Langmuir; 2024 Aug 20; 40(33):17710-17721. PubMed ID: 39119715.
    Abstract:
    Enhanced oil recovery (EOR) is utilized in the oil and gas production industry to extract additional oil from underground reservoirs. In chemically enhanced oil recovery, surfactant and polymeric water are injected separately or in a mixture. Injected fluids can form stable emulsions during oil production. This surfactant, polymer-loaded water-in-oil emulsion, must be separated to treat crude oil and avoid any corrosion or deactivation of catalysts in the refinery. An electrocoalecer technique is utilized to separate the water from the emulsion under the application of an electric field. To improve the efficiency of the EOR and electrocoalescers, it is essential to investigate the impact of surfactants, polymers, and their mixture interaction. In this study, the effects of surfactant (sodium dodecyl sulfate (SDS)), polymer (hydrolyzed polyacrylamide (HPAM)), and their mixture with a wide range of concentrations were analyzed using turbiscan, bottle electrocoalecer, interfacial tension (IFT), and conductivity. Our study shows that when SDS was used independently, the viscosity of the dispersed phase did not change. Surprisingly, when SDS was combined with HPAM, the overall viscosity of the dispersed phase mixture decreased. HPAM and SDS contribute to an increase in the conductivity of the dispersed phase. Conductivity, IFT, and viscosity are critical factors in studying electrocoalescence. Our detailed study found that SDS is the primary factor in stabilizing the emulsion compared to HPAM using turbiscan. The electrocoalecer study shows that in the case of a deionized water-based emulsion, the separation efficiency is 98% in 10 min. In contrast, a mixture of HPAM polymer with a concentration of 2000 ppm and SDS with a concentration of 5000 ppm stabilized emulsion shows 84% separation in 10 min. The outcome of this study helps design the electrocoalescer for separating complex water-in-oil emulsion.
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