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  • Title: Synthesis of Sulfoxides by Palladium-Catalyzed Arylation of Sulfenate Anions with Aryl Thianthrenium Salts.
    Author: Jin F, Hu Q, Wang Q, Sun J, Huang K, Yan CG, Han Y, Fei H, Wang L.
    Journal: J Org Chem; 2024 Sep 20; 89(18):13319-13328. PubMed ID: 39225729.
    Abstract:
    A novel and highly efficient Pd-catalyzed arylation of sulfenate anions with aryl thianthrenium salts is demonstrated. This procedure provides a practical protocol to synthesize various diaryl and alkyl aryl sulfoxides in moderate-to-good yields. The new approach shows mild reaction conditions, broad substrate scope, and good functional group tolerance.
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